N.S. Kurnakov Institute of Unorganic and General Chemistry, Russian Academy of Sciences, Moscow, Russia
The Institute of Colloid Chemistry and the Chemistry of Water, Ukrainian Academy of Sciences, Ukraine
The Institute of New Chemical Problems, Russian Academy of Sciences, Chernogolovka, Russia
Russian Journal of Coordination Chemistry, 1995, v. 21(5), pp. 355-357
The deuterated chloroform and methylenchloride solutions of ZnX2(C10H24N4) (X=Cl, BH4; C10H24N4=1,4,8,11-tetraasocyclotetradecane) were studied by 1H, 11B, 13C and 14N NMR spectroscopy, as well as the solution of ligand itself. The conformational data obtained were compared with the data of RStA for ZnCl2(C10H24N4). It was determined that these compounds have zinc atom shifted from the center of the ligand molecule in the crystalline form, but not in solution.